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Process Data set: Diatomite (diatomaceous silica), not dried; Technology mix; Production mix, at plant (en) en

Key Data Set Information
Location GLO
Geographical representativeness description Global dataset. Global data has been used for the foreground and global and European data for the background systems. The DQI has been adjusted to declare the achieved quality of the data set.
Reference year 2012
Name
Base name ; Treatment, standards, routes ; Mix and location types
Diatomite (diatomaceous silica), not dried; Technology mix; Production mix, at plant
Use advice for data set Notice: this data set supersedes the EF3.0-compliant version (see link under "preceding data set version" below calculated with the EF3.0). The life cycle inventory is not changed from the original EF3.0 data set. The LCIA results are calculated based on the EF3.1 methods which provide updated characterisation factors in the following impact categories: Climate Change, Ecotoxicity freshwater, Photochemical Ozone Formation, Acidification, Human Toxicity non-cancer, and Human Toxicity cancer. The review report and the data quality ratings refer to the original results. The data set has been updated by the European Commission on the basis of the original EF3.0 data set delivered by the data provider.
Technical purpose of product or process Chemical substance used in the production of decorative coatings
Complementing processes
Classification
Class name : Hierarchy level
  • ILCD: Materials production / Organic chemicals
General comment on data set The dataset represents the manufacture of raw materials for the paint industry. It is based on the models created for the CEPE Raw Material database, version 3 (European Council of the Paint, Printing Ink and Artists' Colours Industry; limited access), which have been updated with PEF-compliant background sources based on Ecoinvent 3.3 and process-based EF-compliant LCI datasets for energy and transport. The inventory is based on literature and background sources, following general assumptions for the paint industry. Biogenic carbon content 0%. Water content 0%
Copyright Yes
Owner of data set
Quantitative reference
Reference flow(s)
Time representativeness
Data set valid until 2024
Time representativeness description Annual average data. No intra-annual or intra-daily differences have been made. Representative data for the year 2012 has been used. Data set valid until end of 2024.
Technological representativeness
Technology description including background system In the technology description below, specific dataset names refer to the original modelling based on Ecoinvent 3.3. They might have been updated using the names of the equivalent EF-compliant datasets (In particular transport, infrastructure, water, heat, energy and waste datasets). No specific data available. Model based on information from similar process, IMA and industry/calculated data for post mining related processes for beneficiation of diatomite from open pit mining. The production steps are mining, crushing, drying and grinding. Process description: • Mining operation based on “CH: Limestone, at mine” (Ecoinvent Centre, 2007). • Crushing, drying and grinding operations based on industry/calculated data for energy demand. Infrastructure excluded. Background Processing of minerals The LCA models include general process data for mining, crushing, grinding and flotation. It has not been possible to obtain specific data for these operations, but the general data sets used can be said to represent typical process data. Mining data apply to open pit. Crushing data include two steps, primary and secondary crusher with an assumed overall particle size reduction from 125 mm to 12.5 mm. Grinding operation for flotation include particle reduction from 12.5 mm to less than 0.1 mm. A general flotation process has been assumed concerning energy use. No specific flotation chemicals have been included. Each process operation has been applied in separate modules. Each module has been used where applicable e.g. only grinding. Yield The yield of a chemical process has been based on literature data for the specific reaction where available. If no such data were available, a default value was used. This default value is based on yields of chemical processes in general, which often range between 90-100%. There are also other losses during the production, such as residues in the production facility etc. A conservative estimation of the overall yield when producing chemicals can thus be around 90%. The unreacted input material has been assumed to end up as waste. Use of heat If no specific information was available regarding type of heat used for a production process, the process “RER: market for heat, in chemical industry” has been used (Ecoinvent 3.3), for which the background datasets were replaced with EF-compliant datasets from the node. This process consists mainly of heat from combustion of natural gas, but also some fuel oil, hard coal and electricity. To calculate the amount of heat needed in a process, two different approaches were used. Two different assumptions have been made regarding the energy use of chemical reactions, depending on whether the reactions are exothermic or endothermic. The classification of chemical reactions into these two categories is based on standard enthalpy of reaction. The main sources of information regarding standard enthalpies of formation were chemistry literature and textbooks, such as NIST (2012) and Atkins & Jones (2005). For exothermic reactions, it has been assumed that no additional energy is needed to produce the chemical of interest. This is a simplification as some energy input is likely needed to start a reaction and to maintain it through mixing, etc. The energy generated through the exothermic reaction could also be used in other chemical processes, but this has also been assumed to be non-existent due to lack of data from a specific site. For endothermic reactions, two methods have been used; • It has been assumed that the total energy consumption for the production of a chemical is 30% higher than the standard enthalpy of reaction. • To calculate the required heat, heat losses were assumed to be 20%, and the specific heat capacity for the polymer to be 2.5 [kJ/kg·K], a default value based on that of common organic substances. 2.5 kJ/kg·K is a conservative estimate of the overall heat use for a production process step. For all condensation reactions, it is assumed some energy is required for distillation of the water, therefore 2.26 MJ/kg water (specific heat of evaporation for water) is assumed to be necessary. Electricity use If no specific information was available regarding type of electricity used for a production process, the process “EU-28+3: Electricity grid mix 1kV-60kV” has been used (EF-compliant datasets).
Flow diagram(s) or picture(s)
  • diagram for Diatomite (diatomaceous silica), not dried (676cab22) Image
  • General diagram, system boundaries, chemPaint Image
LCI method and allocation
Type of data set Partly terminated system
LCI Method Principle Attributional
Deviation from LCI method principle / explanations None
LCI method approaches
  • Substitution - average, no correction
Deviations from LCI method approaches / explanations No multi-product problems are identified in the foreground system. In the background system, multi-product datasets are converted to single-product datasets with the help of database wide modelling rules, by partitioning. After the handling of wastes and recyclable materials, allocation takes place over all remaining products produced within the activity. By default, it allocates exchanges from multi-output processes according to their revenue. In the foreground system, circular-footprint formula (CFF) approach is applied; the systems does not contain end-of-life co-product or secondary material input in the foreground. The background data uses EF compliant datasets when available, with respective implementation of the CFF approach. When no EF complaint dataset is available, the background is modelled with use of the datasets based on the “Recycled content cut-off” approach to allocate end-of-life by-products and secondary materials. This allocation is explained in the description of the recycled content system model (http://www.ecoinvent.org/database/system-models-in-ecoinvent-3/cut-off-system-model/allocation-cut-off-by-classification.html).
Modelling constants Direct Land Use change: Land use is inventorised through the use of data on: • Land occupation for the current land use (the occupied land is prevented from changing to a more natural state). • Land transformation (from previous land use and to current land use, e.g., the conversion of a former natural area to industrial land; the conversion of a gravel quarry to a natural area by active re-cultivation). Direct land use change is accounted for on the basis of a 20 year time period and implemented in the calculation of Climate Change according to the PAS2050-1:2012 method and Land Use. It should be noted that the land use classes are not intended to capture specific emissions, such as the CO2 emissions after forest clearing. Such emissions are therefore separately included in the datasets for the specific crops that are grown on such recently transformed land. Carbon storage and delayed emissions: All emissions are considered and therefore no credits are given. Emissions off-setting: No offsets are considered. Time period: No time discounting is reported. Emissions and removals are modelled as if released or removed at the beginning of the assessment method. GHG Emission fossil: All GHG emissions from fossil fuels (including peat and limestone) are modelled consistently with the most updated EF list of elementary flows on the foreground and ILCD list of elementary flows on the background. Carbon emissions and uptakes (biogenic): A distinction is made between fossil and non-fossil sources of CO2, CO and CH4. The sources of fossil carbon are the resource inputs of fossil fuels, peat, and mineral carbonates . The resource consumption of “Carbon dioxide, in air” is calculated from the carbon in harvested plants and wild animals and increases in carbon stored in soils and plants. The latter is recorded as an output of “Carbon dioxide, to soil or biomass stock”. “Carbon dioxide, in air” is the only source of non-fossil carbon, which is mainly captured through the biological photosynthesis. Carbon emissions – land use and land use change: Reductions in the carbon stored in soils and the release of carbon from the burning of biomass residues in connection to land transformation, e.g. the clear-cutting of primary forests, are recorded in the elementary exchange (resource) “Carbon, organic, in soil or biomass stock”. No land use and land use change is modelled in the foreground systems. Capital goods (including infrastructures) and their End of Life: The activity datasets for production infrastructure are included in the averaged background datasets, effectively accounting for the infrastructure. The activity datasets include the maintenance of the infrastructure during its lifetime, its land occupation and land transformation, and its decommissioning for waste treatment.
Deviation from modelling constants / explanations Carbon emissions – land use and transformation in the backgrounds: Reductions in the carbon stored in soils and the release of carbon from the burning of biomass residues in connection to land transformation, e.g. the clear-cutting of primary forests, are recorded in the elementary exchange (resource) “Carbon, organic, in soil or biomass stock”. All of this input is included in the corresponding emissions of Carbon dioxide, Carbon monoxide, and Methane, all with the addition “…, from soil or biomass stock”, and therefore does not contribute to any carbon content of any intermediate exchanges (Overview and methodology Ecoinvent. Section 5.6.2 Fossil and non-fossil carbon).
Data sources, treatment and representativeness
Data cut-off and completeness principles Cut-offs: LCI modelling has been done based on literature sources, theoretical models and by adapting available data sets from databases. When modelling production of chemicals, a number of general assumptions have been used together with stoichiometric calculations. The background models include impacts of infrastructure, yield, heat and electricity and water. At primary level, datasets are as complete as the sources allow, with no cut-off applied. Capital goods (including infrastructures) and their End of Life: The activity datasets for production infrastructure are included in the averaged background datasets, effectively accounting for the infrastructure. The activity datasets include the maintenance of the infrastructure during its lifetime, its land occupation and land transformation, and its decommissioning for waste treatment. System boundaries: System boundaries include all processes linked to the product supply chain, i.e. extraction, production, transport, consumption and waste treatment activities. The supply chain activities are accounted for in the averaged datasets.
Deviation from data cut-off and completeness principles / explanations No strict quantitative cut-off rule is followed in the background sources. No predefined, limited list of elementary exchanges is applied. Full completeness in elementary exchanges is aimed for. The cut-off rule threshold of 95% is satisfied.
Data selection and combination principles Data is consistently based on literature sources, theoretical models and adapted datasets from databases. The relevant background data is sourced from EF3.0 core databases and EF3.0 for chemicals. When processes in these databases were not available, ecoinvent v3.3 database was used (www.ecoinvent.org).
Deviation from data selection and combination principles / explanations None
Data treatment and extrapolations principles No adjustments and extrapolations are performed at primary level.
Deviation from data treatment and extrapolations principles / explanations None
Data source(s) used for this data set
Percentage supply or production covered 0 %
Completeness
Completeness of product model All relevant flows quantified
Supported impact assessment methods
Completeness elementary flows, per topic
  • Particulate matter/respiratory inorganics: All relevant flows quantified
  • Renewable primary energy consumption: All relevant flows quantified
  • Non-renewable primary energy depletion: All relevant flows quantified
  • Renewable material resource consumption: All relevant flows quantified
  • Non-renewable material resource depletion: All relevant flows quantified
  • Land use: All relevant flows quantified
  • Radioactivity: All relevant flows quantified
  • Terrestric eco-toxicity: All relevant flows quantified
  • Seawater eco-toxicity: All relevant flows quantified
  • Freshwater ecotoxicity: All relevant flows quantified
  • Human toxicity: All relevant flows quantified
  • Acidification: All relevant flows quantified
  • Eutrophication: All relevant flows quantified
  • Summer smog: All relevant flows quantified
  • Ozone depletion: All relevant flows quantified
  • Climate change: All relevant flows quantified
Validation
Type of review Scope / Method(s) of review Data quality indicators
Independent external review
Scope name Method name
Unit process(es), single operation
  • Expert judgement
  • Documentation
Documentation
  • Expert judgement
  • Documentation
LCIA results
  • Sample tests on calculations
  • Documentation
LCI results or Partly terminated system
  • Expert judgement
  • Documentation
  • Overall quality: Fair - 2.5
  • Methodological appropriateness and consistency: Not applicable
  • Precision: Fair - 2.9
  • Geographical representativeness: Fair - 2.8
  • Time representativeness: Good - 2.4
  • Technological representativeness: Good - 2.0
Reviewer name and institution Complete review report
Compliance Declarations
Compliance
Compliance system name
Approval of overall compliance
Fully compliant
Nomenclature compliance
Fully compliant
Methodological compliance
Fully compliant
Review compliance
Fully compliant
Documentation compliance
Fully compliant
Quality compliance
Not defined
Compliance
Compliance system name
Approval of overall compliance
Fully compliant
Nomenclature compliance
Fully compliant
Methodological compliance
Fully compliant
Review compliance
Fully compliant
Documentation compliance
Fully compliant
Quality compliance
Fully compliant
Compliance
Compliance system name
Approval of overall compliance
Fully compliant
Nomenclature compliance
Not defined
Methodological compliance
Fully compliant
Review compliance
Fully compliant
Documentation compliance
Not defined
Quality compliance
Not defined
Compliance
Compliance system name
Approval of overall compliance
Fully compliant
Nomenclature compliance
Not defined
Methodological compliance
Fully compliant
Review compliance
Not defined
Documentation compliance
Fully compliant
Quality compliance
Not defined
Compliance
Compliance system name
Approval of overall compliance
Not defined
Nomenclature compliance
Fully compliant
Methodological compliance
Not defined
Review compliance
Not defined
Documentation compliance
Not defined
Quality compliance
Not defined
Commissioner and goal
Commissioner of data set
Project Provision of "Chemicals for paints" process-based product environmental footprint-compliant life cycle inventory datasets. Contract number: 070201/2019/819371/SER/ENV.B.l.
Intended applications To be used in the implementation of a regular Product Environmental Footprint (PEF) studies and Organisation Environmental Footprint (OEF) studies exclusively under the specified Product groups and sectors as defined in the Product Environmental Footprint Category Rules (PEFCR) and Organisation Environmental Footprint Sectorial Rules (OEFSR) listed in http://ec.europa.eu/environment/eussd/smgp/PEFCR_OEFSR.htm and in accordance with the terms and conditions of the EULA exclusively until 31st December 2024.
Data generator
Data set generator / modeller
Data entry by
Time stamp (last saved) 2022-11-21T07:17:22.953+01:00
Data set format(s)
Data entry by
Publication and ownership
UUID 676cab22-6c36-4d4a-b5a4-83733ec768d3
Date of last revision 2022-01-28T07:59:32+01:00
Data set version 03.01.000
Preceding Data set version
Workflow and publication status Data set finalised; entirely published
Owner of data set
Copyright Yes
Reference to entities with exclusive access
License type Free of charge for some user types or use types
Access and use restrictions To be used for the implementation of regular Product Environmental Footprint (PEF) studies and Organisation Environmental Footprint (OEF) studies exclusively under the specified Product groups and sectors as defined in the Product Environmental Footprint Category Rules (PEFCR) and Organisation Environmental Footprint Sectorial Rules (OEFSR) listed in http://ec.europa.eu/environment/eussd/smgp/PEFCR_OEFSR.htm and in accordance with the terms and conditions of the EULA (available at https://lcdn-cepe.org/) exclusively until 31st December 2024. Any use of this dataset or any derivative data not within the specific context of one of the PEF/OEF projects or after the end of 2024 is not permitted.

Inputs

Type of flow Classification Flow Location Mean amount Resulting amount Minimum amount Maximum amount
Product flow Other Services / Other services 1.0 kg1.0 kg
Product flow Other Services / Other services 1.0 kg1.0 kg

Outputs

Type of flow Classification Flow Location Mean amount Resulting amount Minimum amount Maximum amount
Product flow ILCD / Materials production / Other mineral materials 1.0 kg1.0 kg
LCIA Method Data set Mean amount Unit Kommentar
7.550975677157367E-5
mol H+ equivalents
0.010372452526842577
kg CO2 Equivalents
8.004737497119E-10
disease incidence
0.07298178034166163
CTUe
1.782191532686E-5
kg N equivalents
1.935873678145E-6
kg P equivalents
2.540094347337E-4
mol N equivalents
1.3080105311028403E-11
CTUh
2.2875828368781677E-10
CTUh
0.003490936063214
kBq U235 equivalents
0.04153391846305
dimensionless (pt)
2.863324064304E-11
kg CFC11 equivalents
5.3540852461197686E-5
kg NMVOC equivalents
0.1687894312676
MJ
6.039764040778E-8
kg Sb equivalents
0.003444653088755
m3-world equivalents